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GATE 2021 PH – Question 23

Thermodynamics and Statistical Mechanics · Classical and quantum statistics · 1 mark · Multiple select

A fermion system has a density of states that increases with energy. With particle number fixed, which statements about its chemical potential $\mu$ and Fermi–Dirac occupation are correct?

  1. The chemical potential decreases as temperature increases.
  2. The chemical potential increases as temperature increases.
  3. The chemical potential is independent of temperature.
  4. The occupation probability of a state at energy equal to the chemical potential is 1/2.

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Correct answer: (A) The chemical potential decreases as temperature increases.; (D) The occupation probability of a state at energy equal to the chemical potential is 1/2.

Explanation

At low temperature, the Sommerfeld expansion gives $\mu(T)\simeq E_F-\frac{\pi^2}{6}(k_BT)^2g\prime(E_F)/g(E_F)$. An increasing density of states has $g\prime(E_F)>0$, so the chemical potential decreases. Also $f(E)=[e^{(E-\mu)/(k_BT)}+1]^{-1}$ gives $f(\mu)=1/2$ directly. Hence A and D. The temperature trend is the usual fixed-number, low-temperature result underlying this question.

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