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GATE 2024 CY – Question 28

Physical Chemistry · Statistical Thermodynamics: Micro-canonical, Canonical and Grand canonical ensembles, Boltzmann distribution, Partition functions and thermodynamic properties. Statistical mechanics of non-interacting systems, ideal monoatomic, diatomic gases, translational, rotational, vibrational and electronic partition functions. · 1 mark · Multiple select

The correct statement(s) related to an ensemble is (are):

  1. an ensemble is a collection of an infinite number of imaginary replications of the system of interest.
  2. all members of an ensemble are macroscopically identical and also have identical microstates.
  3. an ensemble average of any macroscopic property of the system is equal to the value of the property averaged over a sufficiently long time.
  4. all systems in a canonical ensemble need NOT have the same composition.

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Show answer and explanation

Correct answer: (A) an ensemble is a collection of an infinite number of imaginary replications of the system of interest.; (C) an ensemble average of any macroscopic property of the system is equal to the value of the property averaged over a sufficiently long time.

Explanation

**Ensemble** (statistical mechanics): a large collection of imaginary copies of the system, each representing a possible state.

Answer **A and C**.

Official GATE 2024 answer key: https://gate2026.iitg.ac.in/doc/download/2024/CYFinalAnswerKey.pdf