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GATE 2019 CY – Question 37

Inorganic Chemistry · Solids: Crystal systems and lattices, Miller planes, crystal packing, crystal defects, Bragg’s law, ionic crystals, structure of AX, AX2, ABX3 type compounds, spinels, band theory, metals and semiconductors, Zeolites and their applications. · 2 marks · Multiple choice

Which is a normal spinel?

  1. MgFe₂O₄
  2. ZnFe₂O₄
  3. CoFe₂O₄
  4. CuFe₂O₄

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Show answer and explanation

Correct answer: (B) ZnFe₂O₄

Explanation

In normal ZnFe₂O₄, Zn²⁺ occupies tetrahedral sites and Fe³⁺ occupies octahedral sites, represented (Zn)[Fe₂]O₄. The other listed ferrites show inverse or mixed cation arrangements in the intended comparison. Thus B is the normal-spinel example.

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