GATE 2023 CH – Question 59
A unimolecular, irreversible liquid-phase reaction $A \longrightarrow P$ was carried out in an ideal batch reactor at temperature $T$. The rate of the reaction ($-r_A$) measured at different conversions $X_A$ is given in the table below. This reaction is also carried out in an ideal continuous stirred tank reactor (CSTR) at the same temperature $T$ with a feed concentration of 1 mol m$^{-3}$, under steady-state conditions. For a conversion of 0.8, the space time (in s) of the CSTR is __________ (in integer).
| $X_A$ | 0 | 0.1 | 0.2 | 0.4 | 0.6 | 0.8 |
|---|---|---|---|---|---|---|
| $-r_A$ (mol m$^{-3}$s$^{-1}$) | 0.45 | 0.35 | 0.31 | 0.18 | 0.11 | 0.05 |
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Correct answer: 16
Explanation
For a CSTR, $\tau = \frac{C_{A0}X_A}{-r_A}$ evaluated at the exit conversion. At $X_A = 0.8$ the rate is 0.05 mol m⁻³ s⁻¹, so $\tau = \frac{1 \times 0.8}{0.05} = 16$ s.