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GATE 2025 CY – Question 57

Physical Chemistry · Rotational Motion: Angular momentum operators (orbital and spin), spherical harmonics and their properties. · 2 marks · Multiple select

If a particle’s state function is an eigenfunction of the operator $\hat L^2$ with eigenvalue $30\hbar^2$, then the possible eigenvalue(s) of the operator $\hat L_z^2$ for the same state function is/are

  1. $10\hbar^2$
  2. $16\hbar^2$
  3. $25\hbar^2$
  4. 0

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Correct answer: (B) $16\hbar^2$; (C) $25\hbar^2$; (D) 0

Explanation

For the angular momentum operators:
$$\hat L^2\psi=l(l+1)\hbar^2\psi,\qquad\hat L_z\psi=m\hbar\psi,\quad m=-l,\dots,+l .$$

**Find $l$.** Solve $l(l+1)=30$: $l=5$ (since $5\times6=30$).

**Allowed values of $m$:** $-5,-4,\dots,0,\dots,+5$, so $L_z^2=m^2\hbar^2$ can be
$$0,\ 1,\ 4,\ 9,\ 16,\ 25\quad(\text{in units of }\hbar^2).$$

Check the options:
- $10\hbar^2$: not a perfect square of an integer $m$ between 0 and 5. ✗
- $16\hbar^2$ ($m=\pm4$): possible. ✓
- $25\hbar^2$ ($m=\pm5$): possible. ✓
- $0$ ($m=0$): possible. ✓

Answer **B, C and D**.