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GATE 2025 CY – Previous Year Questions with Solutions

All 65 questions of GATE 2025 CY with answers and explanations. Read each question, then practise it by topic or as a full paper.

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  1. Question 1 (1 mark, Multiple choice) – Courage : Bravery :: Yearning : Select the most appropriate option to complete the analogy.
  2. Question 2 (1 mark, Multiple choice) – We tennis in the lawn when it suddenly started to rain. Select the most appropriate option to complete the above sentence.
  3. Question 3 (1 mark, Multiple choice) – A 44 digital image has pixel intensities (U) as shown in the figure. The number of pixels with U4 is:
  4. Question 4 (1 mark, Multiple choice) – In the given figure, the numbers associated with the rectangle, triangle, and ellipse are 1, 2, and 3, respectively. Which one among the given options…
  5. Question 5 (1 mark, Multiple choice) – A rectangle has a length L and a width W, where L > W. If the width, W, is increased by 10%, which one of the following statements is correct for all…
  6. Question 6 (2 marks, Multiple choice) – Column-I has statements made by Shanthala; and, Column-II has responses given by Kanishk. Column-I Column-II --- --- P. This house is in a mess. 1.…
  7. Question 7 (2 marks, Multiple choice) – Weight of a person can be expressed as a function of their age. The function usually varies from person to person. Suppose this function is identical…
  8. Question 8 (2 marks, Multiple choice) – A regular dodecagon (12-sided regular polygon) is inscribed in a circle of radius r cm as shown in the figure. The side of the dodecagon is d cm. All…
  9. Question 9 (2 marks, Multiple choice) – If a real variable x satisfies 3x2=279x, then the value of 2x2(2x)2 is:
  10. Question 10 (2 marks, Multiple choice) – The number of patients per shift (X) consulting Dr. Gita in her past 100 shifts is shown in the figure. If the amount she earns is ₹1000(X-0.2), what…
  11. Question 11 (1 mark, Multiple choice) – The phosphazene compound that acts as a superbase is
  12. Question 12 (1 mark, Multiple choice) – The reaction for the synthesis of Me2SiCl2 through Rochow-Müller process is
  13. Question 13 (1 mark, Multiple choice) – Upon cooling from room temperature, the magnetic susceptibility of MnO slowly increases until 118 K, and then it decreases. This phenomenon is known…
  14. Question 14 (1 mark, Multiple choice) – An aqueous solution of Co(ClO 4) 26H 2O is light pink in colour. Addition of conc. HCl results in an intense blue coloured solution due to the…
  15. Question 15 (1 mark, Multiple choice) – For an unambiguous single step synthesis of the following target molecule (TM), the best bond disconnection in its retrosynthetic analysis is (TM)
  16. Question 16 (1 mark, Multiple choice) – In the 1H-NMR spectrum of the following molecule, the signal of proton H a appears as
  17. Question 17 (1 mark, Multiple choice) – A disaccharide X does NOT show mutarotation in aqueous solution. Acidic hydrolysis of X affords two different monosaccharides. The disaccharide X is
  18. Question 18 (1 mark, Multiple choice) – The symmetry element that does NOT belong to C 4v point group is
  19. Question 19 (1 mark, Multiple choice) – Rigid rotor wavefunctions are given by Y l,m(,). The wavefunctions Y 1,0(,) and Y 2,0(,) are given below Y 1,0=34, Y 2,0=516(32-1). For a non-polar…
  20. Question 20 (1 mark, Multiple choice) – The translational, vibrational, and rotational molecular partition functions for a system containing ideal diatomic gas molecules in the canonical…
  21. Question 21 (1 mark, Multiple select) – The Vaska’s complex trans-IrCl(CO)(PPh3)2 shows a band at 1967 cm-1 for the νCO stretching vibration in its infrared spectrum. The complex(es) that…
  22. Question 22 (1 mark, Multiple select) – Under the conditions mentioned for each reaction, the reaction(s) that would give borazine (B3N3H6) as the major product is/are
  23. Question 23 (1 mark, Multiple select) – The essential symmetry(ies) for a monoclinic crystal system is/are the presence of
  24. Question 24 (1 mark, Multiple select) – Compound(s) that show(s) an intense peak at m/z 120 in the EI mass spectrum is/are
  25. Question 25 (1 mark, Multiple select) – The correct option(s) of reagents and reaction sequences suitable for carrying out the following transformation is/are
  26. Question 26 (1 mark, Multiple select) – Among the given options, the possible product(s) that can be obtained from the following reaction is/are
  27. Question 27 (1 mark, Multiple select) – Choose the correct option(s) with regard to mechanism of the following transformation.
  28. Question 28 (1 mark, Multiple select) – Two noninteracting particles are confined to a one-dimensional infinite box. Their wavefunctions are 1, 2 and energies E 1,E 2. The INCORRECT…
  29. Question 29 (1 mark, Multiple select) – The thermodynamic criterion/criteria for a spontaneous process is/are
  30. Question 30 (1 mark, Numerical answer) – Xe and F 2 in 1:1 molar ratio when mixed in a closed flask and kept in the sunlight for a day, gave white crystals of a compound Q. Two equivalents of…
  31. Question 31 (1 mark, Numerical answer) – The total number of hyperfine lines expected in the EPR spectrum of CH 2OH (radical) is (in integer). [Note: Consider all hydrogen atoms for…
  32. Question 32 (1 mark, Numerical answer) – Partial hydrolysis of a pentapeptide yields all possible tripeptides and dipeptides. The dipeptides that are obtained upon hydrolysis are given below.…
  33. Question 33 (1 mark, Numerical answer) – The specific rotation of enantiomerically pure (S)-2-butanol is +14°. The specific rotation of enantiomeric mixture of 2-butanol obtained from an…
  34. Question 34 (1 mark, Numerical answer) – The ratio of the fundamental vibrational frequencies ( 13C16O/ 12C16O) of two diatomic molecules 13 C16 O and 12 C16 O, considering their force…
  35. Question 35 (1 mark, Numerical answer) – The expressions for the vapour pressure of solid (p 1) and vapour pressure of liquid (p 2) phases of a pure substance, respectively, are p…
  36. Question 36 (2 marks, Multiple choice) – The reaction that proceeds through an oxidative addition followed by a reductive elimination is [Given: Atomic numbers Ni = 28, Ta = 73, Zr = 40, Pt =…
  37. Question 37 (2 marks, Multiple choice) – The homogeneous catalyst whose metal ion does NOT undergo either oxidation or reduction in any of the steps during the hydrogenation of terminal…
  38. Question 38 (2 marks, Multiple choice) – The given zirconocene compound, (5-Cp) 2ZrEt 2, when heated in the presence of an equimolar amount of PMe 3 results in the formation of a compound X…
  39. Question 39 (2 marks, Multiple choice) – The 1H NMR spectrum of the given iridium complex at room temperature gave a single signal at 2.6 ppm, and its 31P NMR spectrum gave a single signal at…
  40. Question 40 (2 marks, Multiple choice) – The effective magnetic moment, eff value for [Cr(H 2O) 6]3+ taking into account for spin-orbit coupling is closest to [Given: Atomic number of Cr =…
  41. Question 41 (2 marks, Multiple choice) – The major products X and Y formed in the following reaction sequences are
  42. Question 42 (2 marks, Multiple choice) – Compound K has a strong IR band at 1680 cm−1. Its 1H NMR data: (ppm) 7.30 (d, J = 7.2 Hz, 2H), 6.8 (d, J = 7.2 Hz, 2H), 3.8 (septet, J = 7.0 Hz, 1H),…
  43. Question 43 (2 marks, Multiple choice) – The major product formed in the following reaction sequences is
  44. Question 44 (2 marks, Multiple choice) – In the following asymmetric transformation, the key aldol reaction involves the attack of
  45. Question 45 (2 marks, Multiple choice) – The correct option with regard to the following statements is (a) Time-independent Schrödinger equation can be exactly solved for Be2+. (b) For a…
  46. Question 46 (2 marks, Multiple choice) – The phase diagram of a single component system is given below. The option with the correct number of degrees of freedom corresponding to the labelled…
  47. Question 47 (2 marks, Multiple select) – An approximate partition function Q(N,V,T) of a gas is given below. Q(N,V,T)=1N!(2 mk BTh2)3N/2(V-Nb)N. The equation of state(s) for this gas is/are…
  48. Question 48 (2 marks, Multiple select) – The compound(s) having structure similar to that of B2H6 is/are
  49. Question 49 (2 marks, Multiple select) – The UV-visible spectrum of [Ni(en) 3]2+ (en = ethylenediamine) shows absorbance maxima at 11200, 18350, and 29000 cm-1. Absorbance maximum Electronic…
  50. Question 50 (2 marks, Multiple select) – Cytochrome P450 (CYP) enzymes catalyze stereoselective C‒H hydroxylation of hydrocarbons in the presence of O2. The correct statement(s) about the…
  51. Question 51 (2 marks, Multiple select) – The complex(es) having metal-metal bond order 3.5 is/are [Given: The atomic numbers of Mo, Cr, Mn, and Re are 42, 24, 25, and 75, respectively.]
  52. Question 52 (2 marks, Multiple select) – Consider the following two reactions and their corresponding Hammett plots. Choose the option(s) that correctly match(es) the points on the graph…
  53. Question 53 (2 marks, Multiple select) – The correct option(s) of reagents and reaction sequences suitable for carrying out the following transformation is/are
  54. Question 54 (2 marks, Multiple select) – The process(es) and/or intermediate(s) through which the following transformation proceeds is/are
  55. Question 55 (2 marks, Multiple select) – For the following reaction, the possible product(s) is/are
  56. Question 56 (2 marks, Multiple select) – Wavefunctions and energies for a particle confined in a cubic box are n x,n y,n z and E n x,n y,n z, respectively. The functions 1, 2, 3, and 4 are…
  57. Question 57 (2 marks, Multiple select) – If a particle’s state function is an eigenfunction of the operator L2 with eigenvalue 302, then the possible eigenvalue(s) of the operator L z2 for…
  58. Question 58 (2 marks, Numerical answer) – An archaeological 14C specimen gives 45 counts per gram of carbon in 5 minutes. Fresh wood gives 20 counts per gram per minute. Background is 5 counts…
  59. Question 59 (2 marks, Numerical answer) – In the following reaction, 13.4 grams of aldehyde P gave a diastereomeric mixture of alcohols Q and R in a ratio of 2:1. If the yield of the reaction…
  60. Question 60 (2 marks, Numerical answer) – The kinetic energies of an electron (e) and a proton (p) are E and 3E, respectively. Given that mass of a proton is 1836 times that of an electron,…
  61. Question 61 (2 marks, Numerical answer) – If a molecule emitting a radiation of frequency 3.100109 Hz approaches an observer with a relative speed of 5.000106\ m\,s-1, then the observer…
  62. Question 62 (2 marks, Numerical answer) – The mean energy of a molecule having two available energy states at =0 J and =4.1410-21 J at 300 K is 10-21 J (rounded off to two decimal places).…
  63. Question 63 (2 marks, Numerical answer) – For the cell reaction, Hg 2Cl 2(s)+H 2(1\ atm)2Hg(l)+2H+(a=1)+2Cl-(a=1) The standard cell potential is E0=0.2676 V, and ( E0/ T) P=-3.1910-4\ V\,K-1.…
  64. Question 64 (2 marks, Numerical answer) – Consider a Carnot engine with a hot source kept at 500 K. From the hot source, 100 J of energy (heat) is withdrawn at 500 K. The cold sink is kept at…
  65. Question 65 (2 marks, Numerical answer) – The Lineweaver-Burk plot for an enzyme obeying the Michaelis-Menten mechanism is given below. The slope of the line is 0.3610-2 s, and the y-intercept…