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GATE 2023 CY – Question 26

Inorganic Chemistry · Organometallics: 18-Electron rule; metal-alkyl, metal-carbonyl, metal-olefin and metal-carbene complexes and metallocenes. Fluxionality in organometallic complexes. Types of organometallic reactions. Homogeneous catalysis – Hydrogenation, hydroformylation, methanol to acetic acid process, olefin metathesis and Wacker oxidation. Heterogeneous catalysis – Fischer-Tropsch reaction, Ziegler-Natta polymerization. · 1 mark · Multiple choice

The organometallic catalyst for the following transformation is

Diagram for GATE 2023 CY question 26
  1. Structure A
  2. Structure B
  3. Structure C
  4. Structure D

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Show answer and explanation

Correct answer: (A) Structure A

Explanation

Two terminal alkenes exchange alkylidene fragments to form acyclic alkene and ethylene. This is ring-closing olefin metathesis, requiring ametal carbene such asthe ruthenium benzylidene Grubbs catalyst in **A**. Wilkinson catalyst hydrogenates, and the carbonyl catalysts shown are for different transformations.