GATE 2024 MT – Question 41
The constitutional undercooling condition for a hypothetical binary alloy of A with solute B during solidification is shown in the figure along with its binary phase diagram. Based on these two schematics, one can conclude that the solute concentration in region X will be ____________ the average composition of the initial liquid phase.

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Correct answer: (A) less than
Explanation
The supplied phase diagram has a positive liquidus slope and solid preferentially takes up B.
Liquid adjacent to the interface is therefore depleted in B.
Its local liquidus temperature is below the far-field liquidus and rises with distance, as shown.
Thus region X has **less B than the initial average, A**.