The GATE Grind

GATE 2020 CY – Question 48

Inorganic Chemistry · Bioinorganic Chemistry: Ion (Na+ and K+) transport, oxygen binding, transport and utilization, electron transfer reactions, nitrogen fixation, metalloenzymes containing magnesium, molybdenum, iron, cobalt, copper and zinc. · 2 marks · Multiple choice

Match reactions P: $R-H+O_2+2H^++2e^-\to R-OH+H_2O$; Q: $O_2+4e^-+8H^+\to2H_2O+4H^+$; R: $2H_2O_2\to2H_2O+O_2$; S: $NH_2CH_2CO_2H\to NH_2CH(CH_2OH)CO_2H$, with I coenzyme B₁₂, II cytochrome P-450, III cytochrome c oxidase, IV catalase.

  1. P–II, Q–I, R–III, S–IV
  2. P–IV, Q–III, R–II, S–I
  3. P–II, Q–III, R–IV, S–I
  4. P–I, Q–IV, R–III, S–II

Practise this question in The GATE Grind →

Show answer and explanation

Correct answer: (C) P–II, Q–III, R–IV, S–I

Explanation

P is monooxygenation by cytochrome P-450, II. Q is oxygen reduction coupled with proton translocation by cytochrome c oxidase, III. R is peroxide disproportionation by catalase, IV. These three unambiguous matches select C. The source then assigns S to coenzyme B₁₂ by elimination; however, the printed glycine-to-serine conversion adds a carbon unit without showing its donor and is not a complete standard B₁₂ rearrangement. The historical wording and grading are preserved with that limitation, rather than asserting the incomplete equation is a balanced B₁₂ reaction.

More Bioinorganic Chemistry: Ion (Na+ and K+) transport, oxygen binding, transport and utilization, electron transfer reactions, nitrogen fixation, metalloenzymes containing magnesium, molybdenum, iron, cobalt, copper and zinc. questions

All Bioinorganic Chemistry: Ion (Na+ and K+) transport, oxygen binding, transport and utilization, electron transfer reactions, nitrogen fixation, metalloenzymes containing magnesium, molybdenum, iron, cobalt, copper and zinc. questions →