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GATE 2020 CY – Question 49

Inorganic Chemistry · Lanthanides and Actinides: Recovery. Periodic properties, spectral and magnetic properties. · 2 marks · Multiple choice

Thermal-neutron fission of $^{235}_{92}U$ through $^{236}_{92}U$ gives primary fragments $^{99}_{41}Nb$ and $^{133}_{51}Sb$. These undergo three and four radioactive decays respectively to stable chain enders X₃ and Y₄. Identify them.

  1. $^{96}_{41}Nb,\ ^{130}_{51}Sb$
  2. $^{99}_{44}Ru,\ ^{133}_{55}Cs$
  3. $^{93}_{38}Sr,\ ^{127}_{35}Ag$
  4. $^{87}_{35}Br,\ ^{124}_{43}Tc$

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Correct answer: (B) $^{99}_{44}Ru,\ ^{133}_{55}Cs$

Explanation

Neutron-rich fission fragments undergo β⁻ decay, which preserves mass number and increases atomic number by one. Three steps take Nb-99 from Z = 41 to Z = 44, Ru-99. Four steps take Sb-133 from Z = 51 to Z = 55, Cs-133. Therefore B. The primary mass sum is less than 236 because fission also releases neutrons; this does not change the beta-chain mass-number reasoning.

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