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GATE 2024 MT – Question 58

Transport Phenomena and Rate Processes · Chemical and electrochemical kinetics · 2 marks · Numerical answer

A nonporous spherical Fe$_2$O$_3$ particle of initial radius $5\times10^{-2}$ m is topochemically reduced by H$_2$. The sharp reactant–product interface remains spherical, and rate is proportional to its area. The unreacted radius after 600 s is ______ $\times10^{-2}$ m (nearest integer). Given: $k=5\times10^{-5}$ m s$^{-1}$.

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Correct answer: 2 to 2

Explanation

Area-proportional reaction gives constant radial retreat speed, $-dr/dt=k$.

Integrating gives $r=r_0-kt$.

Thus $r=0.05-(5\times10^{-5})(600)=0.02$ m.

The requested coefficient is **2**.