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GATE 2026 BM – Question 38

Biomaterials and Tissue Engineering · Biomaterial Properties · 2 marks · Multiple choice

LCST polymers become less water-soluble as temperature rises. At low temperatures, hydrogen bonding between their ____ (I) segments and water dominates; at high temperatures, interactions between ____ (II) segments dominate.

  1. I hydrophilic; II hydrophobic
  2. I hydrophobic; II hydrophilic
  3. I hydrophilic; II polar
  4. I hydrophobic; II polar

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Correct answer: (A) I hydrophilic; II hydrophobic

Explanation

Hydrophilic segments stabilize low-temperature hydration through favourable interactions with water, including hydrogen bonding. On heating past the LCST, dehydration and hydrophobic association favour chain collapse and phase separation. Therefore I is hydrophilic and II hydrophobic, A.

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