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GATE 2022 CY – Question 33

Organic Chemistry · Experimental Techniques in Organic Chemistry: Optical rotation (polarimetry). Application of various chromatographic techniques such as thin-layer, column, HPLC and GC. Applications of UV-visible, IR, NMR spectroscopy and Mass spectrometry in the structural determination of organic molecules. · 1 mark · Numerical answer

The number of peaks in the broadband proton-decoupled $^{13}C$ NMR spectrum of T, recorded at 25 °C in $CDCl_3$, is ______.

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Correct answer: 8 to 8

Explanation

The molecular symmetry pairs the 14 aromatic carbons into seven equivalent pairs. The two methyl carbons are also equivalent and form one additional environment. Broadband proton decoupling removes C–H splitting without merging distinct chemical environments.

Therefore there are **8 signals**.