The GATE Grind

GATE Environmental Chemistry: Principles of Water Chemistry – Previous Year Questions

18 GATE previous year questions on Principles of Water Chemistry (Environmental Chemistry, Environmental Science and Engineering) with answers and explanations, from every paper.

  1. GATE 2021 ES Q27 (1 mark, Multiple choice) – Water has H⁺ concentration10 mg/L. Hydrogen atomic mass1 g/mol. Find pH.
  2. GATE 2021 ES Q41 (2 marks, Multiple choice) – A 200 mL sample atpH9 requires 25 mL of .02 N H₂SO₄ to reachpH4.5. Find total alkalinity in mg/L as NaHCO₃. Atomic masses Na23,H1,C12,O16,S32,Ca40.
  3. GATE 2021 ES Q63 (2 marks, Numerical answer) – Water containsNa⁺ .25 M, Ca²⁺ .12 M, Cl⁻ .32 M, HCO₃⁻ .05 M. Find ionic strength in M, to two decimals.
  4. GATE 2021 ES Q64 (2 marks, Numerical answer) – Excess solid CaSO₄ is added to pure water atpH7,with undissolved solid remaining. Ksp=2.1×10⁻⁵ mol²/L². Find equilibrium sulfate concentration in…
  5. GATE 2022 ES Q15 (1 mark, Multiple choice) – Specific conductance indirectly estimates dissolved solids in water. Which species contribute to the measurement?
  6. GATE 2022 ES Q21 (1 mark, Multiple choice) – For recarbonation,1 L solution contains 1 mol/L supersaturated calcium carbonate. How many grams CO₂ completely convert it to dissolved calcium ions?
  7. GATE 2022 ES Q54 (2 marks, Numerical answer) – Water at pH6 contains .001 mol/L zinc ions. Zinc hydroxide Ksp=8×10⁻¹⁸ (mol/L)³. Ignore activities. Find reaction quotient/Ksp, to two decimals.
  8. GATE 2022 ES Q55 (2 marks, Numerical answer) – CO₂ Henry constant at 25°C is .034 M/atm in neutral water. CO₂·H₂O⇌H⁺+HCO₃⁻ has K₁=4.3×10⁻⁷ M; HCO₃⁻⇌H⁺+CO₃²⁻ has K₂=4.7×10⁻¹¹ M. Ambient CO₂300 ppm.…
  9. GATE 2023 ES Q14 (1 mark, Multiple choice) – A water sample is colorless with phenolphthalein but yellow after methyl-orange addition. Which alkalinity interpretation is intended?
  10. GATE 2023 ES Q50 (2 marks, Numerical answer) – Gas A has aqueous solubility16 mg/L at vapor pressure.042 atm and 25°C. In a closed system its gas concentration is 10⁻³ mol/L. Use ideal R=.0821…
  11. GATE 2024 ES Q38 (2 marks, Multiple choice) – A saturated CaCO 3 stock solution is at 25°C. Experiment(i) adds25 g Na 2CO 3;experiment(ii) adds25 g Na 2SO 4. Which describes the calcium…
  12. GATE 2024 ES Q50 (2 marks, Numerical answer) – A buffer contains .1 M acetic acid and .05 M sodium acetate. Given pKa4.76,find pH, to two decimals.
  13. GATE 2024 ES Q51 (2 marks, Numerical answer) – Find ionic strength of a solution containing.01 M CaCl 2 and .001 M Na 2SO 4,in M, to three decimals.
  14. GATE 2024 ES Q54 (2 marks, Numerical answer) – Mix2 MLD wastewater at 45°C, pH2 with 3 MLD at 30°C, pH8. Neglect buffering and temperature effects on pH. Find mixed pH, to two decimals.
  15. GATE 2025 ES Q36 (2 marks, Multiple choice) – A researcher adds HgCl 2 to water at pH 10 and calculates expected mercury concentration from the added mass. An instrument measuring only free Hg2+…
  16. GATE 2025 ES Q37 (2 marks, Multiple choice) – Label regions I–IV of the phosphoric-acid speciation diagram.
  17. GATE 2026 ES Q51 (2 marks, Numerical answer) – For SO 2(aq) H++HSO 3- and HSO 3- H++SO 32-,the ideal equilibrium constants are K S1=1.310-2 M and K S2=6.610-8 M. At pH 4.0 and [SO 2(aq)]=1.0 M,…
  18. GATE 2026 ES Q52 (2 marks, Numerical answer) – The figure calibrates absorbance against chromate concentration (CrO 42-,mg/L). For sample absorbance .35,find Cr(VI) concentration in mg/L, to two…