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GATE 2021 CY – Previous Year Questions with Solutions

All 65 questions of GATE 2021 CY with answers and explanations. Read each question, then practise it by topic or as a full paper.

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  1. Question 1 (1 mark, Multiple choice) – Getting to the top is than staying on top.
  2. Question 2 (1 mark, Multiple choice) – Which diagram is the mirror image of the word TRIANGLE about the x-axis?
  3. Question 3 (1 mark, Multiple choice) – In a company, 35% of the employees drink coffee, 40% of the employees drink tea and 10% of the employees drink both tea and coffee. What % of…
  4. Question 4 (1 mark, Multiple choice) – Define p q=(p2+q2)/(pq) and p q=p2/q. If x y=22, then x equals .
  5. Question 5 (1 mark, Multiple choice) – Four persons P, Q, R and S are to be seated in a row, all facing the same direction, but not necessarily in the same order. P and R cannot sit…
  6. Question 6 (2 marks, Multiple choice) – Statement: Either P marries Q or X marries Y Among the options below, the logical NEGATION of the above statement is:
  7. Question 7 (2 marks, Multiple choice) – Consider two rectangular sheets, Sheet M and Sheet N of dimensions 6 cm x 4 cm each. Folding operation 1: The sheet is folded into half by joining the…
  8. Question 8 (2 marks, Multiple choice) – Five equal-length line segments PR, PS, QS, QT and RT form the star shown. The value of θ is degrees.
  9. Question 9 (2 marks, Multiple choice) – Define (p,q)=cases(p-q)2,&p q\+q,&p<q.cases Evaluate (-(-3+2),(-2+3))(-(-2+1)).
  10. Question 10 (2 marks, Multiple choice) – Humans have the ability to construct worlds entirely in their minds, which don’t exist in the physical world. So far as we know, no other species…
  11. Question 11 (1 mark, Multiple choice) – The rates of alkaline hydrolysis of the compounds shown below follow the order:
  12. Question 12 (1 mark, Multiple choice) – The major product formed in the following reaction is:
  13. Question 13 (1 mark, Multiple choice) – The major product formed in the following reaction is:
  14. Question 14 (1 mark, Multiple choice) – The least acidic among the following compounds is:
  15. Question 15 (1 mark, Multiple choice) – The major product formed in the following reaction is:
  16. Question 16 (1 mark, Multiple choice) – The reagent(s) required for the conversion of hex-3-yne to (E)-hex-3-ene is/are:
  17. Question 17 (1 mark, Multiple choice) – An organic compound has molecular-ion peaks [M]+, [M+2]+ and [M+4]+ in ratio 1:2:1 and a singlet at δ 7.49 in its 1H NMR spectrum in CDCl 3. The…
  18. Question 18 (1 mark, Multiple choice) – LiAlH 4 reacts with one equivalent of Me 3N HCl to give a tetrahedral compound, then another equivalent of Me 3N HCl gives N. Identify N and its…
  19. Question 19 (1 mark, Multiple choice) – Which one of the following is a non-heme protein?
  20. Question 20 (1 mark, Multiple choice) – A correct example of a nucleotide is:
  21. Question 21 (1 mark, Multiple choice) – For 3NO(g) N 2O(g)+NO 2(g) at 25 °C, G=-104.18 kJ. With R=8.314 J mol-1 K-1, the equilibrium constant is closest to .
  22. Question 22 (1 mark, Multiple choice) – The reaction of NiBr2 with two equivalents of PPh3 in CS2 at –78 °C gives a red-colored diamagnetic complex, [NiBr2(PPh3)2]. This transforms to a…
  23. Question 23 (1 mark, Multiple choice) – The rate of the substitution reaction of [Co(CN)5Cl]3– with OH– to give [Co(CN)5(OH)]3–
  24. Question 24 (1 mark, Multiple choice) – The octahedral splitting o of [Cr(H 2O) 6]3+, [CrF 6]3- and [Cr(CN) 6]3- follows .
  25. Question 25 (1 mark, Multiple select) – The phase diagram of CO2 is shown below: The correct statement(s) about CO2 is/are:
  26. Question 26 (1 mark, Multiple select) – Acceptable wavefunctions for a quantum particle must be:
  27. Question 27 (1 mark, Multiple select) – The characters of E,C 2, v, v, in that order, for valid irreducible representations of C 2v are .
  28. Question 28 (1 mark, Multiple select) – The normal mode(s) of vibration of H2O is/are:
  29. Question 29 (1 mark, Numerical answer) – A reversible heat engine absorbs 20 kJ of heat from a source at 500 K and dissipates it to the reservoir at 400 K. The efficiency of the heat engine…
  30. Question 30 (1 mark, Numerical answer) – Among the following eight compounds, the number of compound(s) which can exhibit stereoisomerism is .
  31. Question 31 (1 mark, Numerical answer) – The Mo–Mo bond order in [(5-C 5H 5)Mo(CO) 2] 2, which obeys the 18-electron rule, is .
  32. Question 32 (1 mark, Numerical answer) – For 2P(s)+3Br 2(l)2PBr 3(l), H=-243 kJ. If 3.1 g phosphorus reacts, the enthalpy change is kJ (two decimal places). Atomic weight of P is 31.
  33. Question 33 (1 mark, Numerical answer) – The number of 1H NMR signals of the illustrated compound at 25 °C in CDCl 3 is .
  34. Question 34 (1 mark, Numerical answer) – A 5 V battery delivers a steady current of 1.5 A for a period of 2 h. The total charge that has passed through the circuit is Coulombs.
  35. Question 35 (1 mark, Numerical answer) – The spin-only magnetic moment of [Co(H 2O) 6]2+ is BM (one decimal place).
  36. Question 36 (2 marks, Multiple choice) – The geometry and the number of unpaired electrons in tetrakis(1- norbornyl)Co respectively, are:
  37. Question 37 (2 marks, Multiple choice) – The yellow color of an aqueous solution of K2CrO4 changes to red-orange upon the addition of a few drops of HCl. The red-orange complex, the oxidation…
  38. Question 38 (2 marks, Multiple choice) – The shapes of ClF 3, XeOF 2, N 3- and XeO 3F 2, respectively, are .
  39. Question 39 (2 marks, Multiple choice) – The metal borides that contain isolated boron atoms are:
  40. Question 40 (2 marks, Multiple choice) – The major product formed in the following reaction is:
  41. Question 41 (2 marks, Multiple choice) – The major product formed in the following reaction is:
  42. Question 42 (2 marks, Multiple choice) – The major product formed in the following reaction is:
  43. Question 43 (2 marks, Multiple choice) – In the following reaction sequence the major products P and Q, respectively, are:
  44. Question 44 (2 marks, Multiple choice) – In a cell, Ag+ from AgNO 3 is reduced at the cathode and Cu oxidizes to Cu2+ at the anode. A 0.7 A current flows for 10 min. The masses of Ag…
  45. Question 45 (2 marks, Multiple choice) – Which of the illustrated compounds can be prepared by nucleophilic substitution?
  46. Question 46 (2 marks, Multiple choice) – In the following reaction the major products X and Y, respectively, are:
  47. Question 47 (2 marks, Multiple choice) – The major products P and Q formed in the following reactions respectively, are:
  48. Question 48 (2 marks, Multiple choice) – The major product formed in the reaction of (2R,3R)-2-bromo-3-methylpentane with NaOMe is:
  49. Question 49 (2 marks, Multiple choice) – The major product formed in the following reaction is:
  50. Question 50 (2 marks, Multiple choice) – Hexane and heptane are completely miscible. At 25 °C, the vapor pressures of hexane and heptane are 0.198 atm and 0.06 atm, respectively. The mole…
  51. Question 51 (2 marks, Multiple choice) – The correct order of Lewis acid strengths of BF2Cl, BFClBr, BF2Br and BFBr2 is:
  52. Question 52 (2 marks, Multiple choice) – The correct order of increasing intensity (molar absorptivity) of the UV-visible absorption bands for the ions [Ti(H2O)6]3+, [Mn(H2O)6]2+, [CrO4]2–,…
  53. Question 53 (2 marks, Multiple select) – The correct statement(s) about the concentration of Na+ and K+ ions in animal cells is/are:
  54. Question 54 (2 marks, Multiple select) – The correct statement(s) about actinides is/are:
  55. Question 55 (2 marks, Numerical answer) – A 400 nm deuterium lamp has power 1 μW. Its photons emitted per nanosecond number (nearest integer). h=6.62610-34 kg m2 s-1; c=3.0108 m/s.
  56. Question 56 (2 marks, Numerical answer) – Initially there is 1 mg radioactive \!60 27Co, half-life 5.27 years. The amount disintegrated in one year is mg (two decimal places).
  57. Question 57 (2 marks, Numerical answer) – An argon atom (40 amu) travels at 250 m/s. Its de Broglie wavelength is pm (one decimal place). N A=6.0221023; h=6.62610-34 kg m2 s-1.
  58. Question 58 (2 marks, Numerical answer) – A substance in cyclohexane has molar absorption coefficient 1710 L mol-1 cm-1 at 500 nm. For a 2 mmol/L solution in a 1 mm cell, the light-intensity…
  59. Question 59 (2 marks, Numerical answer) – The fundamental vibration of \!1H127I is 2309 cm-1. Its force constant is N/m (nearest integer). N A=6.0221023; c=3.0108 m/s.
  60. Question 60 (2 marks, Numerical answer) – A 532 nm laser Raman spectrometer records Cl 2 with fundamental vibration 560 cm-1. The Stokes line is observed at cm-1 (nearest integer).
  61. Question 61 (2 marks, Numerical answer) – Toluene (molecular weight 92) has vapour pressure 0.13 atm at 25 °C. Dissolving 6 g hydrocarbon in 92 g toluene lowers it to 0.12 atm. The hydrocarbon…
  62. Question 62 (2 marks, Numerical answer) – For CO(g)+Cl 2(g) COCl 2(g) at 500 °C, initial pressures are 0.7 bar CO and 1.0 bar Cl 2. At equilibrium, COCl 2 partial pressure is 0.15 bar. The…
  63. Question 63 (2 marks, Numerical answer) – Decomposition in oxygen has rate constants 0.23710-4 L mol-1 s-1 at 0 °C and 2.6410-4 at 25 °C. Its activation energy is kJ/mol (one decimal place).…
  64. Question 64 (2 marks, Numerical answer) – A 2 L gas at 1 atm is heated reversibly to a final volume of 3.5 L. The absolute work done on the gas is J (nearest integer).
  65. Question 65 (2 marks, Numerical answer) – The quantity of cobalt ore Co 3(AsO 4) 2 H 2O needed to obtain 1 kg Co is kg (two decimal places). Atomic weights: Co 59, As 75, O 16, H 1.